Port Orange is a city in Volusia County, Florida, United States. The city's estimated population was 57,203 in 2013. The city is part of the Deltona-Daytona Beach-Ormond Beach, Florida Metropolitan Statistical Area; the metropolitan area's population in 2010 was 590,289. Port Orange is a principal city in the Fun Coast region of the state of Florida.Port Orange was settled by John Milton Hawks, who brought freed blacks to work at his sawmill after the U.S. Civil War. Esther Hawks established an integrated school in the area. The colony struggled soon after its creation and most colonists left. The area that became known as Freemanville is a legacy of the settlers who stayed in the area.